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A food web is multiple of food chains and that is the reason why the food chain is similar to it. Unlike the Food chain, The food web has a lot of consumers. The producer may be eaten by one or more first consumer and the same goes for the secondary consumer and among the secondary consumer they might end up eaten by either one or two Tertiary consumer. 

This is the only thing that came in to my mind. Hope it helps. ^.^ 
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